{"id":16969,"date":"2025-01-06T10:48:47","date_gmt":"2025-01-06T09:48:47","guid":{"rendered":"https:\/\/www.icpf.cas.cz\/?p=16969"},"modified":"2025-01-06T10:52:58","modified_gmt":"2025-01-06T09:52:58","slug":"photocatalytic-degradation-of-pharmaceuticals-by-visible-light-using-thin-films-of-graphitic-carbon-nitride","status":"publish","type":"post","link":"https:\/\/www.icpf.cas.cz\/en\/photocatalytic-degradation-of-pharmaceuticals-by-visible-light-using-thin-films-of-graphitic-carbon-nitride\/","title":{"rendered":"Photocatalytic degradation of pharmaceuticals by visible light using thin films of graphitic carbon nitride"},"content":{"rendered":"<p style=\"text-align: justify;\">The release of pharmaceuticals and their metabolites into the environment poses pollution risks with consequences for fauna and flora that are not yet fully known or understood.\u00a0 Photocatalytic degradation of these substances by graphitic carbon nitride (<em>g<\/em>-C<sub>3<\/sub>N<sub>4<\/sub>) using visible light could reduce these risks. In this work, <em>g<\/em>-C<sub>3<\/sub>N<sub>4 <\/sub>was investigated in two different forms for the degradation of three selected antibiotics: tetracycline, trimethoprim, and sulfamethoxazole. Emphasis was placed on investigating the description of degradation pathways, modeling the mechanism, and comparing the two photoreactor systems. <em>g<\/em>-C<sub>3<\/sub>N<sub>4<\/sub> in powder form was studied in a batch photoreactor, while <em>g<\/em>-C<sub>3<\/sub>N<sub>4<\/sub> in the form of photocatalytic film was studied in a photomicroreactor with a slit geometry. It was found that during the photo-oxidation processes, the oxidation products of the starting material predominate in the reaction mixture, while degradation products of smaller molecular weight are directly mineralized. A comparison of the batch photoreactor and the microreactor with the developed photocatalytic film showed that the photomicroreactor could use incident radiation more efficiently to degrade the investigated substances.<\/p>\n<p style=\"text-align: justify;\">This study was carried out in cooperation between the <a href=\"https:\/\/www.icpf.cas.cz\/en\/department\/vyzkumna-skupina-mikroreaktoru-en\/\" target=\"_blank\" rel=\"noopener\">Research Group of Microreactors<\/a>, the Faculty of Chemistry at Brno University of Technology, and the Faculty of Science at Masaryk University in Brno.<\/p>\n<p style=\"text-align: center;\"><a href=\"https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024.png\" data-rel=\"lightbox-image-0\" data-rl_title=\"\" data-rl_caption=\"\" title=\"\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-16967 \" src=\"https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024.png\" alt=\"\" width=\"552\" height=\"264\" srcset=\"https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024.png 6375w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-300x143.png 300w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-1024x489.png 1024w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-768x367.png 768w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-1536x733.png 1536w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-2048x978.png 2048w, https:\/\/www.icpf.cas.cz\/wp-content\/uploads\/2025\/01\/Stavarek-2024-370x177.png 370w\" sizes=\"auto, (max-width: 552px) 100vw, 552px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li>Schimon D., Sm\u00edtkov\u00e1 K., Stav\u00e1rek P.*, Jaklov\u00e1 N., Vanluchene A., Dzik P., Homola T., Za\u017e\u00edmal F., Kluso\u0148 P.: A complex study of photocatalytic oxidation pathways of antibiotics with graphitic carbon nitride\u2013The way towards continuous flow conditions. <em>J. Environ. Chem. Eng.<\/em> <strong>2024<\/strong>, <em>12<\/em>, 114801. <a href=\"https:\/\/doi.org\/10.1016\/j.jece.2024.114801\" target=\"_blank\" rel=\"noopener\">doi.org\/10.1016\/j.jece.2024.114801<\/a><\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>The release of pharmaceuticals and their metabolites into the environment poses pollution risks with consequences for fauna and flora that are not yet fully known or understood.\u00a0 Photocatalytic degradation of these substances by graphitic carbon nitride (g-C3N4) using visible light could reduce these risks. In this work, g-C3N4 was investigated in two different forms for&hellip;<\/p>\n","protected":false},"author":19,"featured_media":16967,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[83],"tags":[],"class_list":["post-16969","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-scientific-achievements"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/posts\/16969","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/users\/19"}],"replies":[{"embeddable":true,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/comments?post=16969"}],"version-history":[{"count":2,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/posts\/16969\/revisions"}],"predecessor-version":[{"id":16971,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/posts\/16969\/revisions\/16971"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/media\/16967"}],"wp:attachment":[{"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/media?parent=16969"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/categories?post=16969"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.icpf.cas.cz\/en\/wp-json\/wp\/v2\/tags?post=16969"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}