Introduction of phosphorus and nitrogen atoms into aromatic structures

Many synthetic strategies attempt to vary the shape and size of the π-conjugated system of aromatic compounds to obtain optimal properties. Recently, an alternative approach has come to the fore, which introduces a heteroatom (phosphorus, nitrogen) into the aromatic backbone, whose specific properties (chiral center on phosphorus, easy change of oxidation state, possibility of derivatization) significantly influence the behavior of the π-framework. This project deals with developing a simple and efficient preparation that introduces phosphorus and nitrogen into aromatic structures. The aim is to apply this approach to synthesizing polyaromatic compounds such as phenacenes, helicenes, or nanographenes containing phosphorus and nitrogen atoms.

Required education and skills:

• master’s degree in organic chemistry,
• experimental skill and practical knowledge of organic synthesis,
• teamwork ability,
• employment contract at ICPF.

Expert Supervisors: Ing. Tomáš Beránek, Ph.D.; Ing. Martin Kos, Ph.D.